Analytical Atomic Spectrometry With Flames And Plasmas 2E

This completely revised second edition of the standard work has been expanded by some twenty percent to include more information on the latest developments and new apparatus. In particular, sections have been added on microplasmas and new types of spectrometers, while that on the rapidly expanding field of speciations with practical examples from life and environmental sciences have been included.

Still in one handy volume, the book covers all the important modern aspects of atomic fluorescence, emission and absorption spectroscopy as well as plasma mass spectroscopy in a readily comprehensible and practice-oriented manner. A thorough explanation of the physical, theoretical and technical basics, example applications including the concrete execution of analysis and comprehensive cross-references to the latest literature allow even newcomers easy access to the methodologies described.

Born in 1948, José Broekaert studied chemistry at the University of Gent, Belgium, graduating in 1970. After receiving his PhD from the University of Gent in 1976 and a stay in Germany as Alexander-von-Humboldt postdoctoral fellow the following year, he was a scientist at the ISAS, Dortmund from 1978 to 1991 and obtained the degree of "Geaggregeerde voor het hoger onderwijs" from the University of Antwerp, Belgium in 1985. He became associate professor at the University of Dortmund in 1991, full professor at the University of Leipzig in 1998 and, in 2002, joined the University of Hamburg. In 1998 he was a visiting Fulbright research scholar at Indiana University, Bloomington, USA. His main research interests include the development of plasma optical emission, atomic absorption and inorganic mass spectrometry methods and their application in solving analytical problems.

BASIC PRINCIPLES.

Atomic structure.

Plasmas.

Emission and absorption of radiation.

Ionization.

Dissociation.

Sources for atomic spectrometry.

Analytical atomic spectrometry.

SPECTROMETRIC INSTRUMENTATION.

Figures of merit of an analytical method.

Optical spectrometers.

Mass spectrometers.

Data acquisition and treatment.

Traceability.

SAMPLE INTRODUCTION DEVICES.

Pneumatic nebulization.

Ultrasonic nebulization.

Hydride generation.

Eletrothermal evaporation.

Direct solids sampling.

Cathodic sputtering.

ATOMIC ABSORPTION SPECTROMETRY.

Principles.

Atomic absorption spectrometers.

Flame atomic absorption.

Electrothermal atomic absorption.

Hydride generation.

Background correction techniques.

Fields of application.

ATOMIC EMISSION SPECTROMETRY.

Principles.

Atomic emission spectrometers.

Flame emission.

Arcs and sparks.

Plasma sources.

Glow discharges.

Laser sources.

Fields of application.

PLASMA MASS SPECTROMETRY.

Principles.

Instrumentation.

Glow discharge mass spectrometry.

ICP mass spectrometry.

Fields of application.

ATOMIC FLUORESCENCE SPECTROMETRY.

Principles.

Figures of merit.

LASER ENHANCED IONIZATION SPECTROMETRY.

Principles.

Figures of merit.

COMPARISON WITH OTHER METHODS.

Power of detection.

Reliability.

Economic aspects.