商品簡介
THE ORGANIC CHEMISTRY LABORATROY
1. Apparatus
2. Safe Laboratory Practice, Removal of Unwanted Material
LABORATORY TECHNIQUES
3. Ebullition and Melting Point Determination
4. Crystallization
5. Purification by Distillation
6. Distillation Under Vacuum and with Steam and Sublimation
7. Isolation of Solutes by Extraction
8. TLC: Pain Killer Analysis and Isolation of Terpenes from Natural Products
9. Chromatography on Silica Gel and Alumina
10. Gas/Liquid Chromatography: Alkene Isomer Analysis
11. Spectroscopy at Infrared Frequencies
12. Nuclear Magnetic Resonance Spectroscopy
13. Mass Spectroscopy
14. Spectroscopy at Ultraviolet Frequencies, Refractive Indices, and Instrumental Organic Analysis
15. Chemistry by Computation
REACTION CHEMISTRY: IONIC AND FREE RADICAL
THE SYNTHETIC EXPERIMENTS
16. Synthesis of 1-Bromobutane
17. Alkyl Halide Reaction Chemistry
18. Chlorination of 1-Chlorobutane
19. Cyclohexene from Cyclohexanol
20. Purification of Cholesterol by Debromination
21. Dichlorocarbene Synthesis
REDUCTION AND OXIDATION REACTIONS
22. Cyclohexanone from Cyclohexanol; Adipic Acid from Cyclohexanone
23. The Solventless Cannizzaro Reaction
24. An Alkyne Coupling Reaction: 2, 7-Dimethyl-3, 5-octadiyn-2, 7-diol
25. Hydrogenation
26. Reduction with Sodium Borohydride of 2-Methylcyclohexanol: Conformational Analysis
27. Cholesterol Epoxidation
REACTIONS ON THE AROMATIC RING
28. Methyl Benzoate Nitration
29. Aromatic Alkylation: The Friedel-Crafts Reaction; Host-Guest Chemistry
30. Mesitylene Alkylation
31. Anthraquinone and Anthracene: Synthesis
32. Friedel-Crafts Acylation of Ferrocene: Acetylferrocene
33. Reactions of Triphenylmethyl Group: Cartion, Anion, and Radical
34. 1,2,3,4-Tetraphenylnaphthalene via Benzyne
35. Benzene to Triptycene
AIDEHYDE AND KETONE REACTIONS
36. Aldehydes and Ketones
37. The Aldol Condensation: Dibenzalacetone
38. Grignard Synthesis: Benzoic Acid and Triphenylmethanol
39. The Wittig and Wittig-Horner Reactions
CARBOXYLIC ACIDS, ESTERS, AND AMINES: SYNTHESIS AND REACTIONS
40. Esterification and Hydrolysis
41. Aspirin Synthesis
42. Barbiturate Synthesis Using a Malonic Ester
43. Amines
44. The Sandmeyer Reaction: Replacement of the Amino Group with Halides
45. Sulfanilamide Synthesis and Bioassay
46. Dyes and Dyeing
47. Martius Yellow
REACTIONS CONJUGATED DIENES
48. Diels-Alder Reaction
49. Bis(cyclopentadienyl) iron (Ferrocene)
50. A Diels-Alder Reaction Puzzle: The Reaction of 2,4-Hexadien-1-ol with Maleic Anhydride
51. Tetraphenylcyclopentadienone
52. Hexaphenylbenzene and Dimethyl Tetraphenylphthalate
A MULTISTEP SYNTHESIS: DERIVATIVES OF 1, 2-DIPHENYLETHANE
53. Catalysis by the Cyanide Ion and Thiamine: The Benzoin Condensation
54. Oxidation of Nitric Acid; Preparation of Benzil from Benzoin; and Synthesis of a Heterocycle: Diphenylquinoxaline
55. Reduction of a Ketone Using Borohydride: Hydrobenzoin from Benzil
56. The Synthesis of 2,2-Dimethyl-1,5-dioxolane; The Acetonide Derivative of a Vicinal Diol
57. Reductive Acetylation of Benzil
58. Bromination and Dehydrobromination: Stilbene and Diphenylacetylene
59. Synthesis of a-Phenylcinnamic Acid Using the Perkin Reaction
60. The Aqueous Passerini Reaction
PHOTOCHEMISTRY
61. Syntheses of Cyalume and Luminol: Chemiluminescence
62. The Synthesis of Benzopinacol Using Photochemistry
BIOCHEMISTRY AND NATURAL PRODUCT CHEMISTRY
63. Sweeteners and Carbohydrates
64. The Synthesis of Virstatin
65. Biosynthesis of Ethanol and Enzymatic Reactions
66. Natural Products Synthesis: The Cockroach Sex Attractant and Camphor
67. Polymers and Recycling of Polymers
68. Chemical Literature
