This unified volume explains the mechanistic basics of tactic polymerizations, beginning with an extensive survey of the most important classes of metallocene and post-metallocene catalysts used to make polypropylenes. It also focuses on tactic stereoblock and ethylene/propylene copolymers and catalyst active site models, followed by chapters discussing the structure of more stereochemically complex polymers and polymerizations that proceed via non-vinyl-addition mechanisms. Individual chapters thoroughly describe tactic polymerizations of a-olefins, styrene, dienes, acetylenes, lactides, epoxides, acrylates, and cyclic monomers, as well as cyclopolymerizations and ditactic structures, olefin/CO polymers, and metathesis polyalkenamers.
An ideal reference and supplementary text, Stereoselective Polymerization with Single-Site Catalysts enables both new and experienced chemists to better understand tactic polymers and select appropriate catalyst systems for their preparation.
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