INORGANIC SYNTHESES, VOLUME 23

The volumes in this continuing series provide a compilation of current techniques and ideas in inorganic synthetic chemistry. Includes inorganic polymer syntheses and preparation of important inorganic solids, syntheses used in the development of pharmacologically active inorganic compounds, small-molecule coordination complexes, and related compounds. Also contains valuable information on transition organometallic compounds including species with metal-metal cluster molecules. All syntheses presented here have been tested.

Stanley Kirschner is the editor of Inorganic Syntheses, Volume 23, published by Wiley.

Chapter One ORGANOMETALLIC COMPOUNDS.

1. (Substituted Thiourea)pentacarbonylchromium(0) Complexes.

2. Dicarbonylnitrosyl {tris(3,5-dimethylpyrazolyl) -hydroborato} molybdenum(III) and Iodo-, Alkoxy-, and Alkylamidomolybdenum(III) Derivatives.

3. Diisacyanide Complexes of Molybdenum(0) and Tungsten(0) and Derived Aminacarbyne Complexes.

4. η⁵-Pentamethylcyclopentadienylcobalt complexes.

5. Diphenyltin Dibromide.

6. Carbonylpentafluorophenylcobalt(I) and (II) Complexes.

7. Potassium μ-Hydrido-bis[pentacarbonylchromium(0)] and Potassium μ-Hydrido-bis[pentacarbonyltungsten(0)].

8. Bis[halo-tetracarbonylmanganese(I)].

9. Sodium Hexacarbonylniobate(-I).

10. Disubstituted Derivatives of Hexacarbonylchromium(0).

11. Pentacarbonylrhenium Halides.

Chapter Two COMPOUNDS OF BIOLOGICAL INTEREST.

12. Metal Complexes of Saccharin.

13. cis- and trans-Dichlorobis(nucleoside) palladium(II), cis- and trans-bis(nucleosidato) palladium(II), and cis- and trans-bis(nucleoside) bis(nucleoside') palladium(II) Dichloride or Tetrakis (nucleoside) palladium(II) Dichloride.

14. [[4,4',4'',4"' -Porphyrin-5,10,15,20 -tetrayltetrakis (l-methylpyridiniumato] (2-)]indium(III) Pentaperchlorate.

Chapter Three STEREOISOMERS.

15. Optically Active cis-Unidentate-dicarbonato, cis-cis-Diunidentate- carbonato, and Glycinato-unidentate Cobalt(III) Complexes.

16. Three Isomers of the trans-(N,N'-(2-aminoethyl)-1-2-ethane-diamine) diamminecobalt(III) Complex Cation.

17. 1,4,8,1l-Tetraazacyclotetradecane-5,7-dione (dioxocyclam) Copper(II) and Aqueous Copper(III) Complexes.

18. Chiral Arene-tricarbonylchromium Complexes: Resolution of Aldehydes.

19. A cis(NO₂), trans(N)-Bis(S-arginine)dinitrocobalt(III) Isomer and its use as a Cationic Resolving Agent.

20. Optically Active Cobalt(III) Complexes of CDTA, EDTA, and PDTA in Non-aqueous Solvents.

21. μ-Carboxylato-di-μ-hydroxo-bis[triamminecobalt(III)] Complexes.

22. Tetrabutylammonium Octachlorodirhenate(III).

23. Molybdenum-sulfur Cluster Chelates.

24. Dirhodium(I) Complexes with Carbon Monoxide and Substituted Nitrogen, Phosphorus, and Sulfur Ligands.

25. Dinuclear Methoxy, Cyclooctadiene, and Barrelene Complexes of Rhodium(I) and Iridium(I).

26. Aqua Ions of Molybdenum.

Chapter Five UNUSUAL LIGANDS AND COMPOUNDS.

27. 1, 2-Bis(dichlorophosphino)ethane.

28. Metal Chelates of 2,2,7-trimethyl-3, 5-octanedione, H(tod).

29. Lanthanoid Crown Ether Complexes.

30. Poly-bis(thiocyanato-N)bis-μ-(1H- 1,2,4-triazole-N², N⁴)metal(II) Complexes with Manganese, Iron, Cobalt, Nickel, Copper and Zinc, and Bis[tris(thiocyanato-N)tris (μ-4H-1,2,3,4-triazole-N¹)nickel(II)-N²,N^2',N^2"]nickel(II).

31. Preparation of Pentaindium Tetrasulfide in Liquid Tin.

32. Salts of Alkyl[2-[1-[(2-aminoethyl)imino] ethyl] phenolato] (1,2-ethanediamine) cobalt(III) and Alkyl[2-[1-](3-aminopropyl)imino]ethyl]phenolato] (1,3-propanediamine) cobalt(III).

33. Complexes of 1,3-Dihydro-1-methyl-2H-imidazole-2-thione with Cobalt(II).

34. Metal Ion-controlled Synthesis and Ring Contraction of a Conjugated, Planar, Hexadentate, Macrocyclic Ligand.

35. Triphenylphosphine Oxide and Bipyridine Oxide Complexes of Cerium(IV).

36. Hexakis(dipheny1phosphinic amide)lanthanoid(III) Hexafluoro

37. Complexes of the Types: K₃[Cr(NO)(CN)₅] and [Cr(NO)(NCS)₂(LL)] (LL = 2,2'-Bipyridine; 1,l0-Phenanthroline).

38. Heteropolytungstates with Unsaturated Heteropolyanions.

39. A General Synthesis for Gold(I) Complexes.

40. Trichloro-diphenylantimony(V).

41. Tungsten and Molybdenum Tetrachloride Oxides.

Special Hazard Notice Appendix.

Index of Contributors.

Subject Index.

Formula Index.